The new RoHs compliant subsititutes/replacements for FR4 have a variety of temperature ratings and inter-layer adhesion ratings. Combine one with a lower temperature rating with some entrapped moisture or air, and no doubt you can get layer seperations.
You need to investigate exactly what laminate your PCB house is using, and check the specifications. Go to the actual laminate web sites for data sheets. I listed the RoHs laminate manufacturers in thread240-151146 . If your PCB house does not have an actual process problem, you may have to carefully specify the laminate.
In the pre-RoHS era, for most board designs you might-of just specified "FR-4" and not paid any more attention. With the higher process temperatures required for RoHs solders, and possible longer dwell times (for solder wetting), the laminate material frequently needs additional closer specification. This situation will probably continue for a few years until the various new materials shake-out and a particular new material formulation becomes popular and generally accepted. A similar situation happened in the early FR-4 era.