pressure / viscosity relationship 2

[subsearobot]

Hello folks,
Any idea of an approximation of the relationship between pressure and viscosity in a hydraulic oil? The oil that I am using is a synthetic.

System will be operating at about 12,000 psi on the pressure side (with the "reservoir" at ~9000psi), and want an idea of the approximate delta in the stated viscosity, which will be either 07 or 15 cst. I have contacted the Mfr, but the information has not been forthcoming- they may not have tested to that pressure, and are hesitant to give estimates.

I realize that temperature and oil chemistry have a strong effect here. I'm just looking for a rough order of magnitude- will the visc double, or just increase by 10% due to pressure?

thanks, as always, for your thoughtful input here.

 

[zdas04]

Your best bet is to get something like REFPROP from NIST and use their equation of state to get a value over a range of pressures. All of the shortcut methods that I've found have been pretty unreliable.

David

 

[Oldhydroman]

Hi again Subsearobot

It is common for hydraulic systems designers to completely ignore the viscosity increase that comes about because of an increase in pressure; even though changes in viscosity make a huge difference to pressure drops through valves, pipes and filters. I suppose we often get away with it because those lines most sensitive to pressure drops (suction lines and drain lines) are usually only ever at low pressures. With subsea systems, however, you can’t ignore it with impunity – no-one else has a “drain” line at 9000 psi.

I know you said yours is a synthetic fluid and the particular chemistry will have a bearing (no pun intended) on the final result, but if the stuff is designed to have any form of lubricating properties then the viscosity will almost certainly increase with pressure. Mineral oils exhibit this property and that’s one of the things that makes mineral oil suitable for use as a lubricant. Water does not have the same property – which is why even a small amount of water in a mineral oil system has such a marked effect on the service life of rolling element bearings. The “damage” to the fluid caused by the water ingress means that the viscosity doesn’t rise to the same level in the film of oil between the balls/rollers and the race. The fluid film will be thinner and there be [more] contact between the microscopic peaks on the two surfaces at any particular load.

For a quick and dirty approximation assume you can assume that the viscosity of a MINERAL OIL doubles for every 350 bar increase in absolute pressure. There's no point in worrying about too much accuracy because the extreme temperature variations cause a greater change of viscosity anyway.

It's also debatable whether or not this should be a linear or exponential relationship. By this I mean if you had grade 15 oil at atmospheric pressure and then raised this to 700 bar, is the viscosity an increase of 15 cSt for each 350 bar rise (giving you 45 cSt) or does the viscosity double for the first 350 bar rise and then double again for the next 350 bar rise (giving you 60 cSt)? At your depths the difference is marginal but you could play safe and assume the worst case. A formula you could use would be: new viscosity = old viscosity x 2^(new pressure ÷ 350). The new pressure is measured in bar.

So the worst case figures are for 12000 psi (828 bar):

For your grade 7 fluid... new viscosity = 7 x 2^(828/350) = 7 x 2^2.36 = 7 x 5.15 = 36 cSt.

For your grade 15 fluid... new viscosity = 15 x 2^(828/350) = 15 x 2^2.36 = 15 x 5.15 = 77 cSt.

I've always found that it is wrong to completely ignore the viscosity increase at depth because it affects the pressure drops across the filters and through the small tubes and hoses. But as long as you make some recognition of the viscosity increase in your circuit design you will be OK. Having an understanding of the effect also helps explain to outside observers why the subsea equipment behaves differently at depth when it all seemed so perfect on the deck.

If you are concerned about pressure drops through pipes and filters then the density is also a consideration. The density of a mineral oil increases with absolute pressure – it’s an effect related to the compressibility of the fluid and its bulk modulus. For mineral oil a good enough approximation is to add 21 kg/m³ per 350 bar increase in absolute pressure (this is roughly linear at the sort of pressures under consideration). The density figures from the manufacturer will be at atmospheric pressure, so if your fluid was 880kg/m³ at atmospheric pressure then it will be about 930kg/m³ at 12000 psi (828 bar).

Getting even more detailed now: the density is dependent on the temperature because of the expansion of the oil as it warms (and contraction as it cools). The manufacturer's datasheet will give you the density at 15°C so, again for mineral oil, decrease the density by 0.7kg/m³ for every one degree above 15°C and increase the density by 0.7kg/m³ for every degree below 15°C.

Sorry – these numbers are good enough for mineral oil but your synthetic fluid might be different. But then again you only asked for some approximations so I hope these will do.

DOL

 

[subsearobot]

Thanks, Oldhydroman, and hi!
your estimates are very helpful. Along with dp over our smaller lines, and filters, a concern for this system is back pressure- I don't want to explode any PBOF housings that share the return line.

I say this as this was one of the causes of hydraulic difficulties on a recent (to remain un-named) deep-diving operation. For a test dive, a tech filled the comps with 46cst(!?) on the deck. At 8000m, the manifold lids ruptured and caused quite a maintenance issue (to say the least). return lines were not sized for ~200cst return flow!

anyhow, thanks again!

 

[Oldhydroman]

Hi Subsearobot (and everyone else who's interested)

I thought you might find some use for the attached calculator. It's a tiny little spreadsheet with a huge calculation in one of the cells which allows you to estimate (to within ±10%) the viscosity of an oil at any temperature. Simply put in the viscosity at 40°C and the viscosity at 100°C (to enable the spreadsheet to calculate the characteristics of the oil) and then put in the temperature at which you want to know the viscosity.

Most fluid datasheets will give you the viscosities at these two temperatures, but if you haven't got the 100°C viscosity then the 'work around' goes like this:

Let's imagine you have the viscosity values at 40°C and 0°C.

1) Put the 40°C viscosity value in the spreadsheet.

2) Guess a typical number for the viscosity at 100°C and put that into the spreadsheet.

3) Ask the spreadsheet to calculate the viscosity at 0°C - the number it gives you will be wrong because one of your viscosity values was a guess.

4) Then use the "goal seek" function to make the newly calculated viscosity at 0°C equal the datasheet value by changing the cell that contains the 100°C guess.

5) You will then have a value for the 100°C viscosity that enables the spreadsheet to work properly.

The values of pour point temperature and flash point temperature are only used to stop the calculation from giving silly answers for viscosity at extremes of temperature - try it and see. If you don't have these two values then just put in some dummy numbers: say -100°C for pour point and 800°C for the flash point.

I've deliberately saved the file as an old version of Excel because not everyone has the latest version available to them. I'm also sure that there will be much more sophisticated versions available on the internet somewhere but this little calculation has served me well for years and I'm happy to share it.

DOL

 

[subsearobot]

thanks, DOL. that's a neat little calculator! definitely goes into my toolbox!