Thanks Nick and Ed. But the "valve metal" I'm talking about is the substrate of an anode, as described below...
These anodes are often referred to as composite anodes. Physically, this term refers to a ductile, corrosion resistant base metal covered with the highly conductive stable film described above. The base metal, titanium, provides the required toughness for the system. The titanium substrate is classified as a "valve metal" or film forming metal. Such metals in their natural state are protected by thin, self-healing, tightly adherent oxide films which are acid resistant and resist the passage of current in the anodic direction. Thus, if an attempt is made to operate a valve metal as an anode, it is necessary to raise the potential of the valve metal surface to a high value in order to pass significant current through the anode.