Resources for nitrogen purging of a vessel for storage

[jistre]

I'm currently trying to write a specification for nitrogen purging of vessels after fabrication to drive the oxygen level down to prevent corrosion. Do any of you know of some good resources that I can read that will give me a good background in setting an acceptable residual oxygen level and performing the calculations to determine number of purge cycles required to reach that level?

Thanks for your help, guys.

 

[ash9144]

Oxygen concentration should be set by the material to be put in the vessel. Check the LEL for the service material and go below that.

 

[25362]

Chemical Process Safety: Fundamentals with Applications
by Crowl and Louvar. Prentice Hall.

 

[gr2vessels]

The Nitrogen is a bit heavier than the air, so if you release slowly the Nitrogen in the vessel, you got a fair chance to displace the air from the vessel, without resorting to multiple purging cycles. However, the Oxygen without water (dry air) cannot corrode anything, so you better focus on drying the air, rather than using expensive purging procedures.
Also, is you must prevent moist air ingrease, you just simply add some Nitrogen to the air at 1 - 5 psi and maintain that pressure with some nozzle blanks and a small bottle of nitrogen to make up any loss of pressure.
Sorry, I don't believe that there is any formal written procedure, it is rather a good practice specification developed by the main stream construction companies for transport and long term storage of carbon steel vessels.
Cheers,
gr2vessels

 

[Glenfiddich]

I was involved in the startup of LPG storage vessels and we nitrogen purged the system before startup. Be sure to specify the nitrogen supply temperature for purging to the supplier. It arrives in liquid form. Ambient is good enough.

The operator who will be purging the vessel should be wearing an air pack and he should have an oxygen sensor which he can use on a vent. When the O2 level is below the limit, the vessel is ready. The idea is to keep purging and checking the oxygen level. Be sure to have people without air packs to keep away from low areas near the purge. Oxygen is slightly heavier than nitrogen so the purging should be at a low point in the piping (ie pump piping vent).

I'd bet one nitrogen truckload should be good enough. Keep the vessel pressurised after purging is complete to check for leaks. Check the pressure a couple of hours after purging. We ended up finding some leaks which would have been a nuisance or a danger.

 

[jistre]

Thanks, guys. Got some good leads there. I think I'm well on my way with this procedure. Appreciate the help.

 

[VikingUK]

You have 21% oxygen at 0 barg in your vessel before you start. Use pv = nRt to work out how much nitrogen you need to pressurise the vessel to 5 times atmospheric. That will dilute your oxygen to 1 %.
Your problem then is to stop air getting back in, are you going to seal the vessel ? If so you have serious problems supplying a vessel full of nitrogen.You will have to formulate handling instructions.
I would rethink your anti corrosion programme if I were you.

 

[SNORGY]

If the issue is corrosion mitigation, I do not think you would need to get to 1% O2, especially if the contents are otherwise dry. How critical is the process service?

If the issue is explosion / fire, I read some guidelines on firefighting that suggest that an effective purge and dilution to around 10% O2 is often adequate.

The procedure by Glenfiddich is completely consistent with one we recently developed for post-blowdown purging of sour flare systems where sweet fuel gas is unavailable.

Depending on pressure of N2 supply and ambient temperature during purge, consider a precision glass thermometer or skin temperature RTD downstream of the point of N2 injection. You probably don't want too many prolonged excursions down to or near the nil ductility temperature. If brittle fracture is deemed a risk, consider some length of austenitic pipe between the N2 supply and the system to be purged.

Regards,

SNORGY.

 

[JimCasey]

Viking UK's math is not in question, but it is unlikely that you're going to pressurize an atmospheric (flat roof) tank to 5 atmospheres. Good practice is not to pressurize an atmospheric tank enough to overcome the weight of the top. With 1/4" steel plate top (disregarding bracing structure if any) the maximum pressure comes out to about 1.8" wc. Cycling of the top would cause fatigue of the top-to-side weld. Overpressure will cause ballooning of the top and damage to the tank.

Gr2 Vessels: Respectfully disagree that N2 is heavier than air. MW of N2 is 28. 20% of air is O2 with Mw of 32. That makes the effective MW of air very close to 29. so N2 is 97% as heavy as air. Unless you are in Houston in July, where there is so much water vapor in the air (MW=18) that it would certainly tip the scales. I really don't think you can count on stratification of the gases, tho', and having condensible water vapor in the tank is a no-no.

Initial purge of the empty tank with a volume of Nitrogen equivalent to the volume of the tank shoud be fine as long as the vent is located in a fairly stagnant area of the tank top and the N2 is introduced gently to prevent agitation/forced mixing/short-circuiting of the N2. Then when the tank is filled the initial N2/Air atmosphere in the tank will be vented off. Any future level/pressure cycles will be replaced with pure N2, so the tank atmosphere will reach an equilibrium of nearly pure N2 in a few days if not sooner.

 

[ARenko]

Others have given some good advice on the method. I'll just add that one of my suppliers builds a lot of vessels for a particlar customer that they purge w/ N2 and pressurize to 4 psi to prevent ingress of air on-route.

JimCasey,
Just to nitpick - no reasonable combination of temp/ humidity will drop the mol weight below 28.

In my operations group they say in one area they operate the temps reach 122F with 85% humidity - if true this would be the highest ever recorded heat index at 333F (current is 167F) and they should be dead from lack of being able to cool themselves.

I'm in Houston and I hyperbolize about the temp humidity, but I know it's not realistic that we get 100F and 90% humidity like people often say - if we did we'd be in the record books.

 

[VikingUK]

Actually my maths was wrong (well I typed it wrong anyway) should read 5%.

I have seen humidity of 65% (and I have seen the hygrometer as well) in West Africa with temps of 41C.

Am I missing something here because I never saw any reference to this question being about floating roof tanks ?

I like djv's 4 psi solution

 

[dcasto]

actually, 100% O2 in a carbon steel vessel will not corrode it if there is no water. You goal should be to dry the vessel. We use dry are to remove the water.