My understanding is the mills prefer Round Corner Square (RCS) over square corner because the corners are very subject to cracking and RCS is much easier to handle. I suppose if the rolling mill does not have contoured rolls, only flat rolls, then they would rather produce square cornered material. I suspect most of the RCS produced is used as reforging stock, the corner configuration is not that important and, since it is easier to handle and less susceptible to corner cracking, it is much more popular. As said above, it is best to check with the supplier if you need a particular configuration.
I hope it wasn't too expensive of a lesson. With titanium, it could be rather expensive.
rp