OP said:
What applications it won't work as composite?
Usually safety applications and/or conditions of high temperature and long load duration. Glazed floor applications are an example. There, even with the layers laminated, it is common to assume that some of the layers will break and therefore will not participate in resisting load in the ultimate limit state.
OP said:
Most glass suppliers I talked to never use laminated glass in windows because it's more expensive and they all use tempered glass.
That's mostly been my experience as well. I've done some very tall, two sided support windows at the top of highrise buildings where tempering alone was insufficient at any reasonable, single lite thickness. While tempering helps with strength a great deal, it doesn't do anything much for stiffness.
OP said:
If you hit it with stone.. what would be more resistant and which breaks easily
Let's compare 9 mm tempered versus 2x4.5 annealed and laminated. I would expect the 9 mm tempered to be able to withstand a much greater load prior to first shatter. However, post-breakage, I would expect the laminated glass to perform much better from a safety perspective as it would tend to hold together well. It depends on what manner of resistance one is seeking in a particular application. First shatter isn't everything.
OP said:
What kind of applications where the 9mm laminated only doesn't use composite action and only the 4.5mm is engaged.
Under the right temperature and load duration conditions, the laminated glass can be relied upon to behave compositely. That is, until, one or the other layer is shattered by impact. It's only when one layer must be assumed to be shattered in this way that non-composite behavior comes into play.
OP said:
For emergency fire entry of fireman in windows during fire.. the laminated glass not so advisable, isn't it?
I've not encountered that as a design criterion myself but I can see the logic in it. I've witnessed testing on glass laminated with SGP. Even with all laminations shattered, it holds together remarkably well. The only realistic way through would be to knock the glass out of it's support framing entirely. Lesser interlayers are probably a bit more amenable to through traffi.
I like to debate structural engineering theory -- a lot. If I challenge you on something, know that I'm doing so because I respect your opinion enough to either change it or adopt it.