Underground utility distribution cable is probably 99% aluminum. Industrial facilities tend to use copper.
The economic tradeoffs are pretty straightforward. With copper, you use a smaller conductor size, but the cable is still much heavier, and more costly, than the equivalent aluminum.
Aluminum requires larger conductor cross section but is much lighter, easier to install, and is cheaper. Since most 15 kv distribution circuits are not all that large anyway, aluminum always wins out.
For industrial facilities or power plants with heavy amperage feeders, and relatively shorter runs, copper makes more sense since it allows fewer conductors and smaller conduits to be used.
Both use the same insulation, so the thermal differences tend to wash out because when using aluminum, a larger size conductor is used.