What is the real problem? I assume warping, rather than the change in color is the real problem.
Warping can be due to any reasons -(1) residual stress from processing which got relieved in service, (2)mechanical overload ether during installation or service, etc.
Was it a welded structure?
Measure hardness of the area where it has discolored. If there is huge difference between the supplied valve hardness and warped material, it might have tempered more. Generally 4130 is suplied around 35-45HRC (25 for oil and gas applications due to SCC). See the microstrcure change, if any.
Refer to a heat treatment book where color change with temperature could be found. If everything fails, call your materials vendor for help.
I am sorry I can't think of any more.