First off, base metal:
Hardness and hardenability of Ca-6NM is quite unique among the martensitic SSs. It is EXTREMELY sensitive to carbon content (you can't ever get carbon that is 'too low' in this alloy). So it would be useful to take a chemistry (in the repair area, since it is a large, i.e., non-homogeneous casting).
Filler metals:
Austenitic SS is perfectly acceptable and commonly done in the field, but it will not eliminate the need for preheat. If you do plan to PWHT, you should use use matching filler (generically, 410NiMo). If not, 308 is preferred over 309 due to superior cavitation resistance. There is a specialty alloy developed by R. Simoneau and others at IREQ which is marketed by Stoody as Hydroloy HQ913 (an expen$ive magic bullet!). Remember that differential alloys will set up a galvanic couple that could enhance cavitation in future.
Preheat:
That will depend on the hydrogen potential of the process. 200F for a low-H process, 250-300F for higher. Heat a wide area (more for mitigation of distortion), and use post-heat of 300F minimum for 2 hours minimum. Strictly follow low moisture practice. NEVER exceed 500F interpass.
Technique:
As mentioned by metengr, a temper bead technique, even a crude one, is beneficial for the HAZ, but also for the weld metal if 410NiMo is used (typically, with matching filler, the weld metal is at greatest risk for hydrogen cracking). The fundamental priciple is: every bead deposited directly onto the CA-6NM base metal should be subsequently tempered by another bead in the following layer. Hold weaving and bead/1st layer thickness to a minimum. SMAW electrode diameter 5/32" max; FCAW/GMAW wire diameter 0.045" max.
Distortion:
The extent of welding described here is more likely to cause permanent distortion than a properly done PWHT. (What is the section thickness?) Austenitic fillers will be slightly worse than martensitic in this respect due to their higher thermal expansion and greater yield strength at high temperature. As always, keep overwelding to an absolute minimum.
Concerning the 212F question: there is no problem getting essentially full martensite transformation at this temperature. Therefore it is not necessary to cool down to room temperature before further heat treatment (unlike P-91, with which this alloy otherwise has several metallurgical parallels).
Neweld:
Whatever you learned about 410SS probably does not apply to CA-6NM. Especially (and crucially) the maximum interpass temperature. Which is why the choice of '410NiMo' as the designation for filler metals was an unfortunate one.
I cut my teeth fighting with heavy-section CA-6NM, until I learned to work with it and finally to love and appreciate it