A lot has been said about mil, thou, inches and millimeters here. But do you know how the relation 1 inch = 25,4 mm came about?
It is one of the first de facto standards that later was accepted as an official standard. Here is how and why:
Henry Ford needed accurate measurements and also standardised measurements in his mass fabrication of motor and other car parts. If he didn't have a standardised measure in all his factories, then the pieces wouldn't fit. Actually, mass production could not exist without standardised measures. So Henry Ford asked the Swedish inventor Carl Edward Johansson to deliver end-gauges (aka Joe-blocks) to Fords factories. Johansson was willing, but there was no fixed relation between inches and millimeters - the NBS was working on it and the Congress also had a say in this matter.
The Congress could not decide - there were a lot of different inches around and each congressman thougt that "his" inch was just right and all the others were more or less wrong, so there was no deciscion in the Congress - and no official relation between the inch and the millimeter in the NBS.
This went on for years, and Henry Ford got more and more irritated. At least he told Carl Edward Johansson to make the end-gauges to a convenient and rational measure and CEJ chose 25,4 mm to an inch and delivered the blocks. And ever after that an inch equals 25,4 mm.
CEJ had a reason to chose 25,4; it allowed to switch from metric to imperial threads in a lathe by using two wheels with 100 and 127 cogs on them. 25,0 mm had been too far off what was used in most states, but 25,4 was close enough to the majority of inches.