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Reliable Method for Stripping Copper Plating from 8620 Components 3

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Maui

Materials
Mar 5, 2003
1,939
We have a carburizing line in our industrial heat treating operation, and are processing typical carburizing grades such as AISI 8620 and 9310. As a part of this process, we use a copper plating bath to selectively apply a thin copper layer as a stop off to prevent certain areas on these parts from absorbing carbon during the carburizing process. After carburizing is completed, we would normally use a chromic acid bath solution to strip the copper from the 8620 parts, but due to increasing regulations and associated costs we have decided to discontinue use of the chromic acid altogether.

We need to identify an alternative stripping method that can be used for reliably removing copper plating from these 8620 parts without etching the base material. I am aware of a few ways to do this, but would like your opinions to help identify the best method for our operation. The preference would be for a method that provides the most reliable service without causing substantial maintenance issues or health hazards (such as chromic and and cynaide salts can). I believe that an electrochemical process would probably be the best approach in this regard, but which one? Please let me know what methods you have used, and with what level of success. What are your thoughts?

Maui

 
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ammonia persulfate (watch the fumes), this will complex the Cu and should not harm the steel. Should take about 10% ammonia.
or strong hydrogen peroxide (be very careful) based pickle solutions. I don't recall specific chemistry, I haven't used any of these for many years.

These guys say that they make strippers, but their web site sucks.


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Plymouth Tube
 
I know that iron III chloride (ferric chloride) is commonly used for printed circuit board etching. Not sure what it would do to the un-plated sections, but it should remove the copper well. It is an acid, so handling precautions apply.



SceneryDriver
 
I skipped FeCl because it will attack the steel.
Likewise for most strong acids.
Though dilute sulfuric might be an option

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Plymouth Tube
 
You might try posting your question on Finishing.com. Lot of knowledgeable people over there when it comes to metal treatments.
 
Arthur,

I don't have any personal experience with these products, but there are a number of commercially available strippers that are routinely used to remove copper plating, e.g. from stainless steel parts that have been cold/warm formed out of copper-plated wire. Here are some examples:



 
Maui,

If you can use an alternative stop-off method, Heatbath's No-Carb Special or No-Carb Green works very well. We carburize 8620 among other grades using this material, which is either painted on critical areas or parts are dipped into a container. Some products may require two applications, you need to allow 30 minutes after application before applying a second coat or sending into the furnace.
 
What about reverse plating, sacrificing the copper from the steel?
 
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