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  1. Jason5000

    Knock-out drum liquid seal leg

    Think plumber's P-trap. The one under your sink serves to keep sewer gases from backing up into your house. Liquid is held in place by gravity and provides a barrier vapors can't get through. In refineries some form of liquid seal is typically found in vacuum system seals, flare drums, sulfur...
  2. Jason5000

    VTB Temperature for flow measurement

    DP based coker charge and heater charge meters are often problematic. As you eluded to, keeping the process fluid out of the impulse lines is usually your best bet. Glycerine filled has provided the best (still not great) reliability for DP measurements in tar service in my experience. I'd...
  3. Jason5000

    Designing Reboiler for 2 Liquid Phases

    I've seen upset conditions in a tower do exactly what ash9144 describes. The tower had a water wash in the overhead system. It was equipped with a thermosyphon reboiler, and the bottoms was not hot enough to boil water at operating pressure. When interface level failed in the overhead...
  4. Jason5000

    SRU (Claus) catalyst destruction

    Crush strength and abrasion loss are typically reported by vendors for SRU catalysts as well. Another thought, how are the rundown legs attached to the condensers in your SRU? The units I've worked with where the seal legs come directly out of the condenser cover plates operate fairly trouble...
  5. Jason5000

    SRU (Claus) catalyst destruction

    I guess fines generation through attrition could cause this, but it seems unusual. Perhaps wetting the catalyst then heating up too fast could popcorn it, if a shutdown cycle was involved. A colleague of mine once shared a story about an SRU so heavily sooted from burning hydrocarbon that it...
  6. Jason5000

    sulfites in amines - why, where do they come from, consequences...

    RogerH is absolutely right about the tail gas unit issue. If you're short on hydrogen or have some catalyst damage, SO2 can breakthrough and form thiosulfate heat stable amine salts. This will likely be coupled with cloudy, low pH quench water, and possibly a lot of quench filter changes. If...
  7. Jason5000

    gas sweetening rules of thumbs

    Here's some rules of thumb to get you started. Start with about 20 real trays for the absorber. 30 real trays for the regenerator, feed on tray 26. Apply a stage efficiency of 30% for amine systems. Reboiler duty equivalent to 1 lb of stripping steam per gallon of amine would be typical...
  8. Jason5000

    Mercury content in the refinery wastewater

    Sulfuric acid and and caustic are where I've had the best luck reducing mercury throughput. Between Alky and Merox units and other various uses they tend to see a lot more bulk use than other chemicals in a refinery. Crude and natural gas might be the only things you actually purchase more of...
  9. Jason5000

    Does H2S degassing technology reduces the H2S content to 3 ppm

    The article at this address provides a good general description of the main commercial processes for sulfur degassing: http://www.worleyparsons.com/GlobalPresence/SouthEastAsia/MumbaiTenders/Documents/Sulphur%20Collection%20with%20Degassing.pdf I can't say if any of these licensors would...
  10. Jason5000

    Sulfur Pastill Crushing strength

    Have you consulted Sandvik? This sounds like their technology.
  11. Jason5000

    Hydrocarbon Vapour/Liquid Equilibrium - Impact of Water

    My gut feel here is that your simulation results are "right". What you are likely seeing the impact of the presence of water vapor on the partial pressure of the hydrocarbon components in the vapor phase. Diluting the light hydrocarbons with another vapor, water in this case, causes more of...
  12. Jason5000

    Hydrocarbons on top of water in sour water storage tank

    I've heard of gravity being used as a monitoring point for systems such as you're proposing. Say you put in a 32 API diesel to start with. As it sponges light ends the API gravity will slowly increase over time. Provided you have skim points to grab an oil sample from you can measure gravity...
  13. Jason5000

    Mercury content in the refinery wastewater

    I've seen elemental mercury found in Crude preheat exchangers. Mercury boils at 674 F; however, it exerts a fairly high vapor pressure. It tends to concentrate in naphtha stabilizer/debutanizer areas. Also, catalyst units tend to be too hot to tie up mercury as amalgem, so the stuff can carry...
  14. Jason5000

    Caustic Carryover in Rundown

    Any chance you have a spray bar or some sort of caustic distributor? I've seen these plug up with caustic salts. At a constant caustic flow rate, the increasing velocity resulting from the fouling produces ever smaller droplets until you hit a droplet size that you just can't separate with the...
  15. Jason5000

    Sour water stripper satbilization tank

    Sour water strippers can be rather challenging units to keep operating, depending on your feed quality. Dissolved solids, heavy hydrocarbon contamination, and other issues can foul towers and exchangers occasionally causing out of cycle shutdowns to address the fouling issues. A nice big...
  16. Jason5000

    Horizontal fixed bed reactor for Claus Tail Gas reduction

    This is a pretty normal configuration for a Claus tail gas treating unit hydrogenation reactor. As Yitbos notes, low pressure drop is key because the upstream Claus plant is a low pressure unit. This vessel is not divided flow; though in some small Claus units you will find a reactor such as...
  17. Jason5000

    Lab sized LPG mercaptan removal problem

    SMR units usually have a guard bed in the front end to protect the reforming catalyst from sulfur in the feed. The company I work for usually gets the stuff from Johnson Matthey or Haldor Topsoe. You can extract mercaptan from LPG pretty effectively with 20 Baume caustic. Without a regen...
  18. Jason5000

    Pump minimum recycle

    A centrifugal pump imparts energy into a fluid in the form of velocity. The shape of the pump then turns that velocity into pressure head. The pump puts energy into the liquid and the liquid carries it away. If there is not enough flow, the temperature of the pump will rise and eventually...
  19. Jason5000

    Chemical cleaning instead of steam purge during refinery S/D

    There is also no better time that chemical cleaning to contaminate your utilities and cause untold headaches. Never count on heat exchanger bundles not leaking. Getting cleaning solutions into your cooling water or condensate systems can really ruin your day. I'd recommend blinding utilities...
  20. Jason5000

    Chemical cleaning instead of steam purge during refinery S/D

    I avoid chemical cleaning wherever possible. Planning it is a hassle, and execution has potential to turn into a real mess. The condensate and/or effluent needs to be carefully controlled and likely captured to avoid upset to the waste water plant or sour water handling systems. That being...

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