Sethoflagos,
I may have spoken too quickly saying the differences between the equations in API 521 3rd and 4th editions were not significant. I said that remembering a comment that a colleague had made when we were discussing the differences and I never bothered to look at it closely till now.
As I said before, the only difference I see between the two editions is the 3rd edition uses the isothermal Mach number where the 4th edition uses the adiabatic Mach number, the difference being the inclusion of k = Cp/Cv in the 4th edition.
Following the method in API 4th edition the Mach number (M) is proportional to k^ -0.5 and fL/D is proportional to M^ -2.
When you combine the effects of the proportionalities, I believe this means the 4th edition will calculate a fL/D by a factor of k greater than what the 3rd edition calculates. As I interpret this, for a given allowable pressure drop in the outlet piping, the 4th edition says the line can be longer than what the 3rd edition will allow. Conversely, for an outlet line of given diameter and length, the 4th edition will calculate a lower pressure drop than the 3rd edition.
With the difference between the two editions being the value of k = Cp/Cv, I suspect that is what you had also found when comparing the other methods using k = 1.3 and finding a difference of about 25% in the results.
For as much difference the calculations in the two editions would indicate, I can't say I'm aware of any errata or techinal inquiry that API has issued that addresses this. I don't own a copy of the 4th edition but have access to it at work and I'm aware of only one errata published in 1999 that was not related to the isothermal method. API had been supporting a Technical Inquiries web page for their publications, but I've had trouble getting to it to check the latest for RP-521.
As far as how conservative the isothermal assumption might be, I would say the comparison should be against an adiabatic assumption but it may be somewhat dependent on what method of calculation you choose. The following gives you an idea of what I've seen but I would encourage you to conduct your own comparison so you don't end up making the mistake I made at the beginning of this post.
Using these conditions which would give a Mach number ~0.5 at the end of the pipe....
3000 lb/hr, MW=29, 100F, Z=0.95, k=1.4,
pipe id=1.939 in, total equivalent length of 15 ft,
14.7 psia at the outlet of the pipe
I find
The API 3rd edition isothermal method gives
Total backpressure = 19.7 psia, dP = 5 psi
Using the method Rbcoulter suggests, Cranes TP410 using the "Y" expansion factor gives
Total backpressure = 19.4 psia, dP = 4.7
The API 4th edition isothermal method gives
Total backpressure = 18.1 psia, dP = 3.4 psi
As additional comparison, I have the AIChE CCPS publication "Guidelines for Pressure Relief and Effluent Handling Systems" which came with a CDROM and a great set of relief valve calculation programs including one for compressible flow. Their program patterned after the analyses of Lapple and Shapiro, assumes adiabatic flow -- an assumption that is generally more realistic than the isothermal approximation. Their method gives basically the same result as Cranes TP410 using the "Y" expansion factor...
Total backpressure = 19.4 psia, dP = 4.7
In regards to the discussion of supersonic flow, I can't say I've ever heard anyone talk about that for relief valves before but I'm sure there are many other things that I haven't heard as well.
In reference to what Rbcoulter was remembering, he was probably referring to the typical converging/diverging nozzle arrangement that is used to purposely achieve supersonic flow...
As you mention, a free jet expansion is also likely to cause supersonic velocities...
But keep in mind that a relief valve is not arranged in such a way to give an unobstructed free jet. The nozzle of the relief valve discharges (impinges) directly against the disc, so I would expect that to dissipate some of the energy so that supersonic velocities are not actually achieveable in a relief valve.