Makes a bit more sense, but still don't understand why the orifice size and capacity is relevant to whether it's leaking or not. PSV's by their very nature are not supposed to be open during normal operation,only during over pressure events which have not been caught by the instrumented safety / shutdown system.
I would suggest that if you find one that is leaking, then note it's supposed set pressure on the name plate, the operating pressure of the line at the time and the design pressure of the relevant line. Then you can see if the operating pressure is too close to the set pressure (normally ~10% below set pressure, but can be less if you have a pilot operated valve) or whether the valve is passing when it shouldn't, hence needs to be maintained and set pressure checked.
To work out what the capacity should be needs a comprehensive review of the process safety calcs, which is not a straightforward task, but unless you've made some serios modifications to the plant since the design, shouldn't be an issue. Still nothing to do with leaking valves though.
I would double check what the client actually wants from this survey in this respect because it sure doesn't make sense to me.
My motto: Learn something new every day
Also: There's usually a good reason why everyone does it that way