Okay, I think I see what you're getting at now. I misunderstood the original question a bit I think. You WANT to generate steam at 180 psi and have superheated steam at 85 for use and are wondering if it'll save money in your particular situation. This doesn't seem to have as neat a theoretical answer as I originally thought.
<begin rambling. This is not meant to be serious.>
Sure, steam with more energy in it will generally be able to heat quicker than steam with less energy, but to heat the rail car from point A to point B always takes the same amount of energy, so the fuel costs should be the same. However, you have inefficiencies in the system that change according to the setpoints of the system. You also have throughput of the railcars to worry about... and so on and so forth.
<end rambling>
You can see how you might be in the situation where you can end up mired in questions, equations, and theory when one inexpensive test is really all you need if you can do it SAFELY (remember, steam holds HUGE amounts of energy and if it gets half a chance, it'll happily maim or kill). Could you take the opportunity to test each of your different operating conditions and generate datasets for each condition? Then, you can chart energy usage and productivity so you can compare how your plant reacts to the different conditions to pick the best.
With this problem, we can sit here all day and talk about the theory, but I think you've just got so much going on trying to modify an existing plant that spending a few weeks performing a conclusive test is going to be much better than trying to pin down all the places where the system will deviate from theory.