Maybe pkaiser and MechITHappens should have an internal discussion and report back to the thread?
Anyway, for both cases, with no experience in boiler construction and operation (but lots in valves, piping and steam engineering), I wonder why this discussion concentrates on chemical and operational features, and not manufacturing failure.
In my opinion, any mechanical device, even if tested OK, should not misbehave in the degree described here. Any qualified repair or improvement should not shuffle the problem around, instead of giving improvement. The discussion seems to mainly eliminate false operation and wrong feeding water quality.
Anyway, when something is wrong, it does not necessary indicate only one wrong factor.
Questions:
Is this an unknown problem for the factory or systematic fault for several boilers?
If happening for several: for same model, different models, bound to certain production dates, constructions, workers, welding, materials etc. etc. Systematic fault?
If this is a 'one off' construction, what is different, some factors mentioned above? Flow for fluid and heating medium?
The heating/cooling of the tubes (and sealing material/surfaces) with shrinking and expanding seems (on suspicion based on discussion above) to contribute to the leakage (note: no detailed knowledge on construction by me). Checking details on sealing surfaces and fastening details and expansion/crimping forces and distribution related to material strength?